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Analysis of the effect of potential cycles on the reflective infrared signals of nitro groups in nanofilms: application of the fractional moments statistics

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dc.contributor.author Nigmatullin, Raoul R.
dc.contributor.author Alekhin, A. P.
dc.contributor.author Baleanu, Dumitru
dc.contributor.author Dinç, Erdal
dc.contributor.author Üstündağ, Zafer
dc.contributor.author Ekşi, Haslet
dc.contributor.author Solak, Ali Osman
dc.date.accessioned 2016-06-16T07:34:07Z
dc.date.available 2016-06-16T07:34:07Z
dc.date.issued 2010-02
dc.identifier.citation Nigmatulin, R.R...et al. (2010). Analysis of the effect of potential cycles on the reflective infrared signals of nitro groups in nanofilms: application of the fractional moments statistics. Electroanalysis, 22(4), 419-426. http://dx.doi.org/10.1002/elan.200900369 tr_TR
dc.identifier.issn 1040-0397
dc.identifier.uri http://hdl.handle.net/20.500.12416/1117
dc.description.abstract The effect of the potential cycles on the reflective IR signals of nitro-groups in nanofilms was studied for the statistical characterization of nitrobenzene (NB) and nitroazobenzene (NAB)-modified glassy carbon (GC) surfaces. Both NB and NAB nanofilms were obtained by the electrochemical reduction of the diazonium tetrafluoroborate salts in acetonitrile using cyclic voltammetry (CV). The modified surfaces were denoted as GC-(NB)(n) and GC-(NAB)(n), respectively, where n indicates the number of CV cycles performed during modification. Reflective IR signals of the normalized NB and NAB nanofilms and GC were used for the quantitative evaluation of the effect of the potential cycles on the reflective IR signals of nitro-groups in nanofilms. The detection and quantitative 'reading' of the influence of number of CV cycles were realized in the frame of a new error controllable approach that was applied for analysis of all available set of data. This approach includes in itself the following basic steps: (a) the procedure of the division (normalization) on the GC spectra, (b) the comparison of the smoothed spectra for their statistical proximity in the frame of the statistics of the fractional moments, (c) extraction of possible calibration parameters for possible calibration of the normalized spectra with respect to the number of CV cycles. These three basic steps are becoming effective for detection of the influence of some external factors. In our case it is important to detect the influence of the factor n characterizing CV cycles tr_TR
dc.language.iso eng tr_TR
dc.publisher Wiley tr_TR
dc.relation.isversionof 10.1002/elan.200900369 tr_TR
dc.rights info:eu-repo/semantics/closedAccess
dc.subject Nitrobenzene tr_TR
dc.subject Nitroazobenzene tr_TR
dc.subject Glassy Carbon Electrode tr_TR
dc.subject Diazonium Salt Reduction Modification tr_TR
dc.subject RAIRS tr_TR
dc.subject Nanosurfaces and Interfaces tr_TR
dc.subject Statistics Of The Fractional Moments tr_TR
dc.subject Calibration Curves tr_TR
dc.subject Thin Films tr_TR
dc.subject Nanostructures tr_TR
dc.title Analysis of the effect of potential cycles on the reflective infrared signals of nitro groups in nanofilms: application of the fractional moments statistics tr_TR
dc.type article tr_TR
dc.relation.journal Electroanalysis tr_TR
dc.contributor.authorID 6981 tr_TR
dc.identifier.volume 22 tr_TR
dc.identifier.issue 4 tr_TR
dc.identifier.startpage 419 tr_TR
dc.identifier.endpage 426 tr_TR
dc.contributor.department Çankaya Üniversitesi, Fen Edebiyat Fakültesi, Matematik Bilgisayar Bölümü tr_TR


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